Page 113 - Chemistry - XI
P. 113

Reduction Half-Reaction             E /  V               Reduction Half-Reaction              E / V
                                                    
                                                                                                              
         Pt  + 2e → Pt                             +1.20        Cu  + 2e → Cu                               +0.34
                  –
           2+
                                                                          –
                                                                   2+
         Br  + 2e → 2Br   –                        +1.09        Hg Cl  + 2e → 2Hg + 2Cl    –                +0.27
                                                                            –
                 –
            2                                                       2  2
         AgCl + e → Ag + Cl    –                   +0.27        S + 2e → S   2–                             –0.48
                  –
                                                                       –
         Bi  + 3e → Bi                             +0.20        In  + e → In  2+                            –0.49
                                                                   3+
                                                                        –
           3+
                  –
                                                                  4+
                                                                        –
         SO  + 4H  + 2e → H SO  + H O              +0.17        U  + e → U    3+                            –0.61
            2−
                          –
                    +
                                2
                                    3
                                         2
            4
         Cu  + e → Cu    +                         +0.16        Cr  + 3e → Cr                               –0.74
                                                                   3+
            2+
                 –
                                                                          –
         Sn  + 2e → Sn   2+                        +0.15        Zn  + 2e → Zn                               –0.76
            4+
                                                                          –
                  –
                                                                   2+
         AgBr + e → Ag + Br    –                   +0.07        Cd(OH)  + 2e → Cd + 2OH      –              –0.81
                                                                              –
                  –
                                                                         2
         Ti  + e → Ti  3+                         + 0.00        2H O + 2e → H  + 2OH      –                 –0.83
                 –
                                                                           –
           4+
                                                                    2            2
                                                  0.0 (by
         2H  + 2e → H                                           Cr  + 2e → Cr                               –0.91
                                                                   2+
                  –
                                                                          –
            +
                        2                       defi nition)
         Fe  + 3e → Fe                             –0.04        Mn  + 2e → Mn                               –1.18
            3+
                                                                    2+
                  –
                                                                          –
                                                                         –
                                                                  2+
                                −
         O  + H O + 2e → HO  + OH      –           –0.08        V  + 2e → V                                 –1.19
                        –
                2
           2
                                2
         Pb  + 2e → Pb                             –0.13        Ti  + 2e → Ti                               –1.63
                                                                         –
                  –
                                                                   2+
            2+
         In  + e → In                              –0.14        Al  + 3e → Al                               –1.66
                                                                   3+
                –
                                                                          –
           +
         Sn  + 2e → Sn                             –0.14        U  + 3e → U                                 –1.79
                                                                         –
                                                                  3+
            2+
                  –
         AgI + e → Ag + I   –                      –0.15        Sc  + 3e → Sc                               –2.09
                                                                          –
                                                                   3+
                 –
         Ni  + 2e → Ni                             –0.23        Mg  + 2e → Mg                               –2.36
                  –
                                                                          –
            2+
                                                                    2+
         V  + e → V   2+                           –0.26        Ce  + 3e → Ce                               –2.48
           3+
                                                                          –
                                                                   3+
                –
         Co  + 2e → Co                             –0.28        La  + 3e → La                               –2.52
                                                                          –
                                                                   3+
            2+
                   –
         In  + 3e → In                             –0.34        Na  + e → Na                                –2.71
                                                                        –
                  –
                                                                   +
           3+
         Tl  + e → Tl                              –0.34        Ca  + 2e → Ca                               –2.87
                                                                   2+
                                                                          –
           +
                –
                                                                   2+
                                                                         –
                     –            2−               –0.36        Sr  + 2e → Sr                               –2.89
         PbSO  + 2e → Pb + SO
               4                  4
         Ti  + e → Ti  2+                          –0.37        Ba  + 2e → Ba                               –2.91
                                                                   2+
                 –
                                                                          –
           3+
         Cd  + 2e → Cd                             –0.40        Ra  + 2e → Ra                               –2.92
                                                                          –
            2+
                                                                   2+
                   –
         In  + e → In  +                           –0.40        Cs  + e → Cs                                –2.92
                                                                   +
                –
           2+
                                                                        –
         Cr  + e → Cr   2+                         –0.41        Rb  + e → Rb                                –2.93
            3+
                 –
                                                                        –
                                                                   +
         Fe  + 2e → Fe                             –0.44        K  +e → K                                   –2.93
            2+
                                                                      –
                  –
                                                                  +
         In  + 2e → In  +                          –0.44        Li  + e → Li                                –3.05
                                                                                                            –3.05
                  –
                                                                       –
                                                                   +
           3+
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