Page 45 - Chemistry - XI
P. 45

Observation Table

                                              Burette readings ________ mL
              S. No. Initial reading of  Final reading       Volume of oxalic acid used        Volume of NaOH
                           burette           of burette               (V ) in mL                  uses in mL
                                                                         1
                1.
                2.
                3.


          Volume of NaOH used (V ) = ________ mL
                                     2
          Calculations
                        M V  = M V , M   = Molarity of acid, M  = Molarity of base
                          1  1    2  2     1                       2
                                         V   = Volume of acid in mL, V  = Volume of base in mL
                                           1                            2
                                                    0.1 × V  =M  × 25, suppose 23 mL of oxalic acid solution is used then
                                           1    2
                                                   0.1 × 23   = M  × 25   or       M  = 0.092 mole/litre
                                                 2                 2
                      Strength of NaOH solution   = M  × Molecular weight
                                                 2
                                               = 0.092 × 40 (M. wt. of NaOH)

                                              = 3.68 g per litre
          Result
          The strength of given NaOH solution is ________ gL    –1.




                                                   EXPERIMENT - 17


          Objective
          To prepare a standard solution of sodium carbonate (M/20).

          Materials Required

          Burette (50 mL), pipette (25 mL), conical fl ask (250 mL), burette stand, funnel, white glazed tile, measuring
          fl ask, and Na CO .
                            3
                        2
          Procedure
          1.  We will prepare 250 mL of M/20 sodium carbonate solution.

          2.  Amount of Na CO  required to prepare M/20 solution in 250 mL        106    250   1 325.  g
                             2   3
                                                                                   20   1000
          3.  Dissolve 1.325 g of Na CO  in distilled water and prepare the standard solution in 250 mL of measuring
                                     2
                                         3
              fl ask by adding required amount of water.
          4.  Thus prepared standard solution of sodium carbonate has molarity M/20 or 0.05 M.







                                                                                                             43
   40   41   42   43   44   45   46   47   48   49   50