Page 42 - Chemistry - XII
P. 42

2+
                                                                              2+
                                                               Zn |Zn||Cu|Cu
                             CuSO  or ZnSO
                                  4
                                            4





                                                                Zn
                                                                2+
                                               2.303RT
                                  E    = E °            log
                                                                2+
                                    cell  cell    n F         Cu


                                                 aq+ 2e Oxidation

                                  Zn s      Zn
                                              2
                                  Cu                Cus      Reduction

                                     2
                                        aq +2e
                                                Zn s+Cu       aq     Zn

                                                                           aq +Cus

                                                                        2
                                                           2

                                  n =2
                                                            Zn
                                                              2+


                                               0.0591
                                  E   = E°            log
                                    cell   cell               2+
                                                  2         Cu

                               E
                                 cell







                     ZnSO .7H O
                           4    2


                           1 M


                     CuSO 5.  HO
                              2
                          4
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