Page 83 - Chemistry - XII
P. 83

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                                                                                       →


                                                             →                                      KFeCN
                                                                                                                6
                                                                                                      4


                                                                                       KFeCN                    →
                                                                                         4
                                                                                                    6








                Pb +H S       PbS +2H    +
                   +2
                        2
                          B   lack ppt.


                PbS+ 2HNO        Pb NO        +H S
                             3          3 2       2
                                                Black pppt.
                Pb NO      +H SO       PbSO     +2HNO

                       3 2    2   4          4           3
                                                 Whiite ppt.





                Pb CH COO+ 2KI           PbI    +2CH COOK
                       3      2             2         3
                                       Yellow ppt.



                Pb CH COO+ KCrO              PbCrO     + 2CHCOOK
                                         4
                                   2
                       3
                                                              3
                                                    4
                              2
                                                        Yellow ppt.

                PbCrO+ 2NaOH         NaCrO +PbOH
                       4                2    4           2
                                       Soluble

                Cu +H S       CuS +2H     +
                   +2
                         2
                             Black ppt.


                3CuS+8HNO         3CuNO        + 2NO+ 4H O+3S
                              3            3 2             2
                Cu NO      +2NH OH        Cu OH       +2NH NO


                        3 2       4         Blue ppt.  2     4   3
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